参考文献(References)：
[1] JIANG Y Y,NI P J,CHEN C X,et al.Selective electrochemical H2O2 production through two-electron oxygen electrochemistry[J].Advanced Energy Materials,2018,8(31):1801909.
[2] KIM H W,ROSS M B,KORNIENKO N,et al.Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts[J].Nature Catalysis,2018,1(4):282.
[3] SAMIRA S,DESHPANDE S,ROBERTS C A,et al.Nonprecious metal catalysts for tuning discharge product distribution at solid-solid interfaces of aprotic Li-O2 batteries[J].Chemistry of Materials,2019,31(18):7300.
[4] BEERS R F,Jr,SIZER I W.A spectrophotometric method for measuring the breakdown of hydrogen peroxide by catalase[J].The Journal of Biological Chemistry,1952,195(1):133.
[5] SONG Z G,KWOK R T K,DING D,et al.An AIE-active fluorescence turn-on bioprobe mediated by hydrogen-bonding interaction for highly sensitive detection of hydrogen peroxide and glucose[J].Chemical Communications,2016,52(65):10076.
[6] HUCKABA C,EKEYES F G.The accuracy of estimation of hydrogen peroxide by potassium permanganate titration[J].Journal of the American Chemical Society,1948,70(4):1640.
[7] GILL T M,ZHENG X L.Comparing methods for quantifying electrochemically accumulated H2O2[J].Chemistry of Materials,2020,32(15):6285.
[8] JIANG Y Y,LU Y Z,LYU X Y,et al.Enhanced catalytic performance of Pt-free iron phthalocyanine by graphene support for efficient oxygen reduction reaction[J].ACS Catalysis,2013,3(6):1263.
[9] LU Z Y,CHEN G X,SIAHROSTAMI S,et al.High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials[J].Nature Catalysis,2018,1(2):156.
[10] JIANG Y Y,DING Z Y,GAO M,et al.Spontaneous deposition of uniformly distributed ruthenium nanoparticles on graphitic carbon nitride for quantifying electrochemically accumulated H2O2[J].Chinese Journal of Chemistry,2021,39(12):3369.
[11] LYU M Z,CHEN M X,ZHANG R,et al.Manganese is critical for antitumor immune responses via cGAS-STING and improves the efficacy of clinical immunotherapy[J].Cell Research,2020,30(11):966.
[12] WALDRON K J,RUTHERFORD J C,FORD D,et al.Metalloproteins and metal sensing[J].Nature,2009,460(7257):823.
[13] SIGNORELLA S,PALOPOLI C,LEDESMA G.Rationally designed mimics of antioxidant manganoenzymes:role of structural features in the quest for catalysts with catalase and superoxide dismutase activity[J].Coordination Chemistry Reviews,2018,365:75.
[14] HUGHEY C C,CRAWFORD P A.Pyruvate carboxylase wields a double-edged metabolic sword[J].Cell Metabolism,2019,29(6):1236.
[15] MALALASEKERA A P,WANG H W,SAMARAKOON T N,et al.A nanobiosensor for the detection of arginase activity[J].Nanomedicine:Nanotechnology,Biology and Medicine,2017,13(2):383.
[16] LIU Y F,CHENG Y,ZHANG H,et al.Integrated cascade nanozyme catalyzes in vivo ROS scavenging for anti-inflammatory therapy[J].Science Advances,2020,6(29):eabb2695.
[17] CHEN F,BAI M,CAO K,et al.Fabricating MnO2 nanozymes as intracellular catalytic DNA circuit generators for versatile imaging of base-excision repair in living cells[J].Advanced Functional Materials,2017,27(45):1702748.
[18] ZHU Y,WANG W Y,CHENG J J,et al.Stimuli-responsive manganese single-atom nanozyme for tumor therapy via integrated cascade reactions[J].Angewandte Chemie International Edition,2021,60(17):9480.
[19] CHEN Y F,JIAO L,YAN H Y,et al.Hierarchically porous S/N codoped carbon nanozymes with enhanced peroxidase-like activity for total antioxidant capacity biosensing[J].Analytical Chemistry,2020,92(19):13518.
[20] LIU W X,HUANG J J,YANG Q,et al.Multi-shelled hollow metal-organic frameworks[J].Angewandte Chemie International Edition,2017,56(20):5512.
[21] HU M,JU Y,LIANG K,et al.Void engineering in metal-organic frameworks via synergistic etching and surface functionalization[J].Advanced Functional Materials,2016,26(32):5827.
[22] DI CASTRO V,POLZONETTI G.XPS study of MnO oxidation[J].Journal of Electron Spectroscopy and Related Phenomena,1989,48(1):117.
[23] CHEN Z J,HUANG Z C,SUN Y M,et al.The most active oxidase-mimicking Mn2O3 nanozyme for biosensor signal generation[J].Chemistry:A European Journal,2021,27(37):9597.
[24] ZHANG C H,CHEN C X,ZHAO D,et al.Multienzyme cascades based on highly efficient metal-nitrogen-carbon nanozymes for construction of versatile bioassays[J].Analytical Chemistry,2022,94(8):3485.
