2026年 05期

摘要(Abstract)：

针对净水厂污泥资源化利用率低、净水过程中土臭素等嗅味物质去除难度大且成本高等问题，通过联用臭氧氧化技术优化净水厂污泥基活性炭(基础组)制备工艺，制得臭氧-净水厂污泥基活性炭(自制组),利用正交实验法优化联用工艺参数，设计自制组与臭氧-商业活性炭(商业组)对照试验，考察自制组的土臭素去除效能，并分析自制组的经济效益。结果表明：基础组的碘值可达493.54 mg/g,多点BET(Brunauer-Emmett-Teller)比表面积为553.416 2 m²/g, DR(Dubinin-Radushkevich)微孔比表面积占比为91.5%,经臭氧氧化，表面生成的含氧官能团有利于吸附土臭素；自制组的土臭素去除率可达92.95%,并且随着进水中土臭素的质量浓度及酸碱度pH的增大，土臭素去除率均表现出先增后减的趋势，当进水中土臭素的质量浓度为150 ng/L且pH为7时，土臭素去除率达到最大值94.26%;自制组与商业组的前30 d出水中土臭素去除率均大于90%,自制组的前15 d出水中土臭素的质量浓度均小于10 ng/L, 30 d后出水中土臭素的质量浓度仍小于商业组的，表明自制组有较强的污染物截留能力，每年可节省成本并获得收益约7.388×10⁶元，经济实用潜力巨大。

关键词(KeyWords)：吸附剂;臭氧-净水厂污泥基活性炭;正交实验法;土臭素;工艺优化

基金项目(Foundation):山东省自然科学基金项目(ZR2023ME143)

作者(Author):怀磊,张守彬,任文祎,李泉荃,肖传晶

DOI:10.13349/j.cnki.jdxbn.20260626.001

参考文献(References)：

[1] GB 5749—2022 生活饮用水卫生标准[S].

[2] 郭蓉蓉，张永，刘淑刚，等.臭氧-活性炭深度处理在饮用水厂除嗅的应用[J].石油化工应用，2024,43(8):86.

[3] 李勇，张晓健，陈超.我国饮用水中嗅味问题及其研究进展[J].环境科学，2009,30(2):583.

[4] 钟志聪，赫俊国，吴学伟，等.臭氧活性炭工艺处理多种新污染物复合污染研究[J].给水排水，2024,60(3):1.

[5] Li Wenhong,Yue Qinyan,Gao Baoyu,et al.Preparation and utilization of sludge-based activated carbon for the adsorption of dyes from aqueous solutions[J].Chemical Engineering Journal,2011,171(1):320.

[6] Nandee R,Chowdhury M A,Hossain N,et al.Surface topography and surface morphology of graphene nanocomposite by FESEM,EDX and AFM analysis[J].Nano-Structures & Nano-Objects,2024,38:101170.

[7] Xu Yonghui,Liu Yufei,Zhan Wei,et al.Enhancing CO2 capture with K2CO3-activated carbon derived from peanut shell[J].Biomass and Bioenergy,2024,183:107148.

[8] Wu Wenjun,Liu Jun,Zhang Guojie,et al.Adsorption of CO2 by sludge/bamboo shoot shell hybrid biochar prepared by a single-step K2CO3 activation[J].Fuel,2025,381:133555.

[9] Messa G N,Jesus A M D d,Fiore F A.Beneficial use of sludge from water treatment plants as a multiple resource:potential and limitations[J].Resources,Conservation & Recycling Advances,2025,25:200247.

[10] GB/T 12496.8—2015 木质活性炭试验方法碘吸附值的测定[S].

[11] Fan Qingwen,Song Chaoyun,Fu Peng.Advances in the improvement of the quality and efficiency of biomass-derived porous carbon:a comprehensive review on synthesis strategies and heteroatom doping effects[J].Journal of Cleaner Production,2024,452:142169.

[12] Zhang Yan,Zhao Yunpeng,Qiu Lele,et al.Insights into the KOH activation parameters in the preparation of corncob-based microporous carbon for high-performance supercapacitors[J].Diamond and Related Materials,2022,129:109331.

[13] Dong Ruihan,Tang Ziyue,Yang Yang,et al.Comprehensive investigation of activator influence on pyrolysis kinetics,thermo-dynamics,and product characteristics in one-step activated carbon preparation from spirulina[J].Bioresource Technology,2025,428:132472.

[14] Li Zhentao,Liu Dameng,Cai Yidong,et al.Adsorption pore structure and its fractal characteristics of coals by N2 adsorption/desorption and FESEM image analyses[J].Fuel,2019,257:116031.

[15] Koundle P,Nirmalkar N,Momotko M,et al.Tetracycline deg-radation for wastewater treatment based on ozone nanobubbles advanced oxidation processes (AOPs):focus on nanobubbles formation,degradation kinetics,mechanism and effects of water composition[J].Chemical Engineering Journal,2024,501:156236.

[16] Paulino R,Tamburic B,Stuetz R M,et al.Critical review of adsorption and biodegradation mechanisms for removal of biogenic taste and odour compounds in granular and biological activated carbon contactors[J].Journal of Water Process Engineering,2023,52:103518.

[17] Bong T,Kang J K,Yargeau V,et al.Geosmin and 2-methyl-isoborneol adsorption using different carbon materials:isotherm,kinetic,multiple linear regression,and deep neural network modeling using a real drinking water source[J].Journal of Cleaner Production,2021,314:127967.

[18] Liu Yucheng,Zhou Sheng,Liu Rui,et al.Utilization of waste sludge:activation/modification methods and adsorption applications of sludge-based activated carbon[J].Journal of Water Process Engineering,2022,49:103111.

[19] Liu Yuman,Wei Guoxia,Liu Hanqiao,et al.Effect of organic/inorganic separation on the adsorption performance of sludge-based activated carbon[J].Journal of Environmental Chemical Engineering,2024,12(6):114861.

[20] Zendelska A,Pancevska V,Golomeova M,et al.Characterization and isothermal studies of Cd removal from aqueous solutions using sludge-based activated carbon[J].Desalination and Water Treatment,2022,276:146.

[21] Thuangchon S,Somboot P,Sungthong B,et al.Dissolved organic matter removal from sugar mill effluent by activated carbon-catalytic ozonation:performance,organic carbon change,system characterization,and catalyst reusability[J].Journal of Water Process Engineering,2025,69:106808.

[22] Peng Denghui,Zhou Guo,An Ke,et al.Critical review on the adsorption of taste and odor compounds by activated carbon:influencing factors,modifications methods,mechanism[J].Chemical Engineering Journal,2025,507:160677.